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Question re: Indirect Painting/Glazing Method

I was contemplating doing a master study, and using a more indirect method where I try to build up multiple layers with transparent colors as the artist used that method. If anyone has worked in that method, did you wait until the final layer to incorporate white? I only ask because white colors are opaque (except for zinc white which I heard is best to avoid as it's fugitive). 
In particular, if you do a grisaille as the first layer, is it advisable to incorporate white at that stage already?


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