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What exactly are the color mixing rules?


We know that

red and blue make purple...

yellow and blue make green...

red and yellow make orange..

Yet this schemata doesn't work for frequencies of light. 
 Mixing blue light and green light makes yellow light. 
 Mix every color light together and one gets white light.  


 How is this possible?  What exactly are the color mixing rules and how do they work?

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